Stereoselective synthesis and reaction of gold(I) (Z)-enethiolates.
نویسندگان
چکیده
Bench-top-storable (Z)-enethiol reagents: gold (Z)-1-decenylthiolates were synthesized stereoselectively in high yields. They are stable upon storage at room temperature without protection from light, and react smoothly with various alkyl halides, α,β-unsaturated ketones, and electron-deficient aryl halides with excellent stereoselectivity.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 37 شماره
صفحات -
تاریخ انتشار 2015